掺烧煤矸石对减轻生物质燃烧结渣性能的影响Effect of coal gangue blending on mitigating slagging performance of biomass combustion
朱愉洁,韩元,柳少卿,贾相如
摘要(Abstract):
生物质含有较多碱金属元素,在燃烧过程中会产生较严重的结渣问题;煤矸石是一种大宗固体废弃物,迫切需要对其进行资源化利用。为解决生物质燃烧结渣和煤矸石利用问题,使用煤矸石作为添加剂,将其与葵花秸秆混合燃烧。采用热重分析(TG-DTG)、电感耦合等离子光谱发生仪(ICP-AES)、灰熔融点测定仪等测试手段对燃烧后的灰样进行理化特性分析,考察温度、配比对混合燃料燃烧性能和结渣的影响。研究结果表明:在葵花秸秆燃烧过程中,加入少量的煤矸石,葵花秸秆灰中的碱金属含量明显升高,并更多地转化为高熔点的硅铝酸盐固定在灰样中,进入气相的碱金属含量减少,从而降低燃烧的结渣倾向;同时葵花秸秆会降低煤矸石的着火点温度和燃尽温度,从而促进煤矸石的燃烧,二者协同作用明显;当煤矸石添加质量分数为20%时,燃料的可燃性指数达到9.36×10~(-4)%/(min·℃),综合燃烧特性指数达到42.6×10~(-7)%/(min~2·℃~3),燃烧性能最佳,软化温度达到1470℃,极大地降低了结渣倾向。
关键词(KeyWords): 葵花秸秆;煤矸石;混合燃烧;结渣;熔融特性
基金项目(Foundation): 内蒙古电力(集团)有限责任公司内蒙古电力科学研究院分公司2023年院自筹(一批)科技项目(2023-ZC-11) ~~
作者(Author): 朱愉洁,韩元,柳少卿,贾相如
DOI: 10.19666/j.rlfd.202408185
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