房孝维,孙瑜,张光晋,张雪华,李兴华,张杰,朱树健

• 1:西安热工研究院有限公司
• 2:中国科学院过程工程研究所
• 3:国家能源费县发电有限公司
• 4:国家能源集团华北电力有限公司廊坊热电厂

摘要(Abstract)：

燃煤烟气中CO_2与N_2的高效资源化利用是推动能源系统低碳转型的重要途径。电化学法耦合烟气中CO_2与N_2直接合成尿素，可在温和条件下将温室气体转化为高附加值化肥，兼具碳减排与资源循环双重效益。系统综述了该领域近期进展，通过异质结、导电MOF等新型催化剂设计优化反应路径，实现N_2与CO_2协同活化及C-N偶联效率提升，最高尿素法拉第效率达48%；未来突破需聚焦仿生催化材料开发、光-电耦合系统集成以及绿电驱动下碳捕集-转化-产物分离一体化工艺创新；从技术原理、工程挑战及产业衔接层面，论证了电催化尿素合成在煤电碳氮协同治理中的关键作用，为推进其规模化应用提供前瞻性策略思考。

关键词(KeyWords)： 燃煤烟气;电催化;尿素合成;CO_2利用;固氮

Abstract:

Keywords:

基金项目(Foundation): 西安热工研究院有限公司院研发基金项目（TD-24-TYK04）~~

作者(Author): 房孝维,孙瑜,张光晋,张雪华,李兴华,张杰,朱树健

DOI: 10.19666/j.rlfd.202503016

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