电渗析用于燃烧后二氧化碳捕集的胺回收技术研究进展Advances in electrodialysis technologies for amine reclaiming in post-combustion carbon dioxide capture
黄艳,胡治平,王玉玮,刘培军,李水飞,胡昔鸣,杨林,方梦祥
摘要(Abstract):
燃烧后CO_2捕集过程中,有机胺吸收剂易降解生成中性降解产物及热稳定盐(heatstable salt,HSS)。电渗析(electrodialysis,ED)技术作为一种常温常压下高效脱除HSS的方法,在胺回收领域具有广阔的应用前景。系统综述了电渗析用于有机胺回收的研究进展,包括不同电渗析装置的构型特点、关键工艺参数(电压、电流密度、初始HSS浓度、CO_2负荷等)对脱除效率、胺损失与能耗的影响机制。重点总结了多段膜堆、电渗析与树脂或双极膜耦合等工艺优化策略,并对不同应用场景下电渗析装置的工业运行性能进行了比较分析。最后,针对膜材料稳定性、能耗与成本控制等挑战,提出了未来电渗析在CO_2捕集胺回收领域的发展方向。
关键词(KeyWords): 降解产物;热稳定盐;电渗析;胺回收;HSS脱除;胺损失
基金项目(Foundation): CCUS化学吸收系统胺基化学吸收剂电渗析回收和再生技术研发项目(CEZB240005324) ~~
作者(Author): 黄艳,胡治平,王玉玮,刘培军,李水飞,胡昔鸣,杨林,方梦祥
DOI: 10.19666/j.rlfd.202502048
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