高汞煤循环流化床锅炉汞的迁移转化及飞灰吸附特性研究Migration characteristics of mercury and mercury adsorption characteristics of fly ash in CFB boiler firing high mercury coal
高新,王泉海,熊得杨,卢啸风,李建波,张戎迪,龙潇飞,张家宝,邹兴东
摘要(Abstract):
为研究我国西南地区燃用高汞煤工业循环流化床(CFB)锅炉中汞的迁移转化特性以及飞灰对汞的吸附特性,使用LumexRA-915M汞在线分析仪对锅炉烟道不同位置烟气进行在线监测,同时对入炉煤、底渣、飞灰、脱硫浆液、脱硫废水等进行取样分析。结果表明:除尘器前烟气中的汞超过87%富集于飞灰中,底渣中汞仅占0.07%,飞灰对汞的富集主要归因于其未燃尽碳(UBC)含量、矿物组成及孔隙结构;锅炉所配备的布袋除尘器和湿法脱硫设备的除汞效率分别为91.19%和51.49%,最终排往大气的烟气汞质量浓度仅为3.43μg/m3,高汞煤在CFB内燃烧汞排放达到了国家排放要求。此外,发现不同粒径下飞灰汞含量与UBC含量有相同趋势,而且飞灰中汞主要富集在飞灰表面并主要是以HgO和Hg0的形式存在。
关键词(KeyWords): CFB锅炉;高汞煤;汞;迁移;飞灰;吸附特性
基金项目(Foundation): 国家重点研发计划项目(2016YFB0600201)~~
作者(Author): 高新,王泉海,熊得杨,卢啸风,李建波,张戎迪,龙潇飞,张家宝,邹兴东
DOI: 10.19666/j.rlfd.202110207
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