席肖桐,田绅,郭璐娜,陈六彪,许成杨,徐伟宸,孙志利

• 1:天津市制冷技术重点实验室天津商业大学
• 2:中国科学院理化技术研究所低温科学与技术重点实验室
• 3:中国科学院大学

摘要(Abstract)：

物理吸附储氢具有安全性能高、储氢密度大及充放氢速率快的优势，是一种极具应用潜力的储氢方式，其中金属有机架构物（MOFs）材料凭借其高度有序的孔隙结构和可调控特性已成为理想的吸氢材料。为探究吸附储氢过程热效应对储氢性能的影响，首先建立了吸附储氢数值模型并进行验证，随后对比分析了Cu-BTC与活性炭AX-21的储氢特性，并探究不同温度下Cu-BTC的储氢能力。计算结果表明：相较于AX-21，采用Cu-BTC作为吸附剂材料，常温下储氢量提升了12.8%；将储氢温度降至77 K时，Cu-BTC储罐的最高压力降至0.97 MPa，储氢质量相较于常温300 K提升了174%。以上结论可为Cu-BTC材料储氢研究提供参考。

关键词(KeyWords)： 储氢;吸附储氢;金属有机架构物;Cu-BTC;低温吸附

Abstract:

Keywords:

基金项目(Foundation): 天津市科学技术局科技帮扶提升重大工程项目（22ZYCGSN00030）~~

作者(Author): 席肖桐,田绅,郭璐娜,陈六彪,许成杨,徐伟宸,孙志利

DOI: 10.19666/j.rlfd.202405108

参考文献(References)：

• [1] ZAINAL B S, KER P J, MOHAMED H, et al. Recent advancement and assessment of green hydrogen production technologies[J]. Renewable and Sustainable Energy Reviews, 2024, 189:113941.
• [2]张盛,郑津洋,戴剑锋,等.可再生能源大规模制氢及储氢系统研究进展[J].太阳能学报, 2024, 45(1):457-465.ZHANG Sheng, ZHENG Jinyang, DAI Jianfeng, et al.Research progress on renewable energy systems coupled with large-scale hydrogen production and storage[J].Acta Energiae Solaris Sinica, 2024, 45(1):457-465.
• [3] HASSAN Q, ALGBURI S, SAMEEN A Z, et al. Green hydrogen:a pathway to a sustainable energy future[J].International Journal of Hydrogen Energy, 2024, 50:310-333.
• [4] RAMPAI MM, MTAHALI C B, SEROKA N S, et al.Green hydrogen:hydrogen production, storage, and transportation:recent advances[J]. RSC Advances, 2024,14(10):6699-6718.
• [5] MUHAMMED N S, GBADAMOSI A O, EPELLE E I,et al. Hydrogen production, transportation, utilization,and storage:recent advances towards sustainable energy[J]. Journal of Energy Storage, 2023, 73:109207.
• [6] LI J Q, LI J C, PARK K, et al. Investigation on the changes of pressure and temperature in high pressure filling of hydrogen storage tank[J]. Case Studies in Thermal Engineering, 2022, 37:102143.
• [7] LI X L, HAO Y M, WU F, et al. Numerical simulation of leakage jet flame hazard of high-pressure hydrogen storage bottle in open space[J]. International Journal of Hydrogen Energy, 2024, 62:706-721.
• [8] LI Y F, LI Q N, PENG W Z, et al. A comparative analysis of the regulations, codes and standards for on-board high-pressure hydrogen storage cylinders[J].International Journal of Hydrogen Energy, 2024, 54:894-907.
• [9] YIN L, YANG H N, JU Y L. Review on the key technologies and future development of insulation structure for liquid hydrogen storage tanks[J].International Journal of Hydrogen Energy, 2024, 57:1302-1315.
• [10]李昆鹏,徐鹏,沈兵权,等.液氢储运技术及标准化[J].化学工程与装备, 2023(1):177-179.LI Kunpeng, XU Peng, SHEN Bingquan, et al.Technology and standardization of liquid hydrogen storage and transportation[J]. Chemical Engineering&Equipment, 2023(1):177-179.
• [11] WANG H R, WANG B, SUN J C, et al. Experimental and computational fluid dynamic investigation on thermal behaviors of liquid hydrogen during the no-vented storage process:a literature review[J]. Journal of Energy Storage, 2024, 57:822-843.
• [12] XU Y H, ZHOU Y, LI YT, et al. Carbon-based materials for Mg-based solid-state hydrogen storage strategies[J].International Journal of Hydrogen Energy, 2024, 69:645-659.
• [13] LI Y T, GUO Q F, DING Z, et al. MOFs-based materials for solid-state hydrogen storage:strategies and perspectives[J]. Chemical Engineering Journal, 2024,485:149665.
• [14] ABDECHAFIK E H, OUSALEH H A, MEHMOOD S,et al. An analytical review of recent advancements on solid-state hydrogen storage[J]. International Journal of Hydrogen Energy, 2024, 52:1182-1193.
• [15] WANG C S, BRINKERHOFF J. Low-cost lumped parameter modelling of hydrogen storage in solid-state materials[J]. Energy Conversion and Management, 2022,251:115005.
• [16] ZHU Z W, ZHENG Q R. Investigation of cryo-adsorption hydrogen storage capacity of rapidly synthesized MOF-5 by mechanochemical method[J].International Journal of Hydrogen Energy, 2023, 48:5166-5174.
• [17]刘木子,史柯柯,赵强,等.固体储氢材料的研究进展[J].化工进展, 2023, 42(9):4746-4769.LIU Muzi, SHI Keke, ZHAO Qiang, et al. Research progress of solid hydrogen storage materials[J].Chemical Industry and Engineering Progress, 2023,42(9):4746-4769.
• [18] SRIVASTAVA S, SHET S P, PRIYA S S, et al. Molecular simulation of copper based metalorganic framework(Cu-MOF)for hydrogen adsorption[J]. International Journal of Hydrogen Energy, 2022, 47:15820-15831.
• [19]邬娇娇,徐向亚,刘东兵,等.金属有机骨架材料在储氢领域的应用[J].化工新型材料, 2023, 51(11):16-21.WU Jiaojiao, XU Xiangya, LIU Dongbing, et al.Application of metal-organic frameworks(MOFs)in hydrogen storage field[J]. New Chemical Materials,2023, 51(11):16-21.
• [20] WU M B, ZHENG Q R, SUN T Q, et al. Analysis of heat conducting enhancement measures on the composite for hydrogen storage by incorporation of activated carbon with MOFs[J]. International Journal of Hydrogen Energy,2023, 48:3994-4005.
• [21]韩笑,贾银娟,刘闯,等.金属有机骨架材料Fe/Cu-BTC的制备及其脱硫性能[J].化学反应工程与工艺, 2023, 39(1):20-28.HAN Xiao, JIA Yinjuan, LIU Chuang, et al. Preparation and desulfurization performance of metal-organic framework material Fe/Cu-BTC[J]. Chemical Reaction Engineering and Technology, 2023, 39(1):20-28.
• [22]李瑞丽,王国江,张东媛,等. Cu-BTC吸附剂对模拟油中有机氯化物的脱除性能[J].石油炼制与化工,2021, 52(8):56-63.LI Ruili, WANG Guojiang, ZHANG Dongyuan, et al.Performance of Cu-BTC for organic chlorides adsorption from model oil[J]. Petroleum Processing and Petrochemicals, 2021, 52(8):56-63.
• [23] LETWABA J, UYOR U O, MAVHUNGU M L, et al. A review on MOFs synthesis and effect of their structural characteristics for hydrogen adsorption[J]. RSC Advances, 2024, 14(20):14233-14253.
• [24] PAZ L, GREKOV D I, PRE P. Dynamics of hydrogen storage through adsorption:process simulation and energy analysis[J]. Processes, 2023, 11(10):2940.
• [25] PENG C C, LIU X Y, LONG R, et al. Performance optimization of adsorption hydrogen storage system via computation fluid dynamics and machine learning[J].Chemical Engineering Research and Design, 2024, 207:100-109.
• [26] YANG D H, LIANG L S, ZHANG H Y, et al. Numerical simulation of the hydrogen charging process in an adsorption storage tank[J]. International Journal of Hydrogen Energy, 2024, 68:673-687.
• [27] XIAO J S, LI Q, COSSENMENT D, et al. Lumped parameter simulation for charge-discharge cycle of cryo-adsorptive hydrogen storage system[J].International Journal of Hydrogen Energy, 2012, 37(18):13400-13408.
• [28] XIAO J S, HU M, BENARD P, et al. Simulation of hydrogen storage tank packed with metal-organic framework[J]. International Journal of Hydrogen Energy,2013, 38:13000-13010.
• [29] YANG J Y, WANG H C, DONG X Q, et al.Performances comparison of adsorption hydrogen storage tanks at a wide temperature and pressure zone[J].International Journal of Hydrogen Energy, 2023, 48:26881-26893.
• [30] KLOUTSE F A, ZACHARIA R, COSSEMENT D, et al.Specific heat capacities of MOF-5, Cu-BTC, Fe-BTC,MOF-177 andMIL-53(Al)over wide temperature ranges:measurements and application of empirical group contribution method[J]. Microporous and Mesoporous Materials, 2015, 217:1-5.