气相色谱法测定矿物涡轮机油中气体Ostwald系数及含气量Ostwald coefficients and contents of gas in mineral turbine oil detected by GC method
王笑微,严涛,尹文波,王腾,张晋玮,王娟,刘永洛
摘要(Abstract):
通过测定50℃时L-TSA 32及L-TSA 46号矿物涡轮机油中溶解气体奥斯特瓦尔德系数(Ostwald系数),经与50℃国产矿物绝缘油中气体Ostwald系数对比及拟合后,发现两者线性相关,给出了利用气相色谱法检测矿物涡轮机油含气量的校正公式及简易换算方法,可为矿物涡轮机油含气量及油中各气体组分含量的检测提供指导。
关键词(KeyWords): 气相色谱法;矿物涡轮机油;矿物绝缘油;溶解气体;Ostwald系数;含气量
基金项目(Foundation): 陕西省技术创新引导专项(基金)计划(2020CGHJ-004)~~
作者(Author): 王笑微,严涛,尹文波,王腾,张晋玮,王娟,刘永洛
DOI: 10.19666/j.rlfd.202107133
参考文献(References):
- [1]SUN H C,HUANG Y C,HUANG C M.A review of dissolved gas analysis in power transformers[J].Energy Procedia,2012,14:1220-1225.
- [2]DUVAL M.A review of faults detectable by gas-in-oil analysis in transformers[J].IEEE Electrical Insulation Magazine,2002,18(3):8-17.
- [3]刘强,何险峰.电容器特征气体浓度检测方法分析[J].电力电容器与无功补偿,2018,39(3):102-105.LIU Qiang,HE Xianfeng.Analysis on detection method of characteristic gas concentration of capacitor[J].Power Capacitor&Reactive Power Compensation,2018,39(3):102-105.
- [4]吕爽,钱壮,黄露,等.变压器油色谱分析二次脱气法研究及应用[J].安徽电气工程职业技术学院学报,2020,25(1):74-78.LYU Shuang,QIAN Zhuang,HUANG Lu,et al.Research and application of secondary degassing for chromategraphic analysis of transformer oil[J].Journal of Anhui Electrical Engineering Professional Technique College,2020,25(1):74-78.
- [5]赵璧,董翔,戴瑞成,等.基于油中溶解气体能量强度的变压器故障案例推理技术研究[J].电力与能源,2020,42(1):20-23.ZHAO Bi,DONG Xiang,DAI Ruicheng,et al.Transformer fault case-based reasoning technology based on energy intensity of dissolved gas in oil[J].Power&Energy,2020,42(1):20-23.
- [6]绝缘油中溶解气体组分含量的气相色谱测定法:GB/T17623-2017[S].北京:中国标准出版社,2017:1-24.Determination of componental contents of gases dissolved in insulating oil by gas chromatography method:GB/T17623-2017[S].Beijing:Standards Press of China,2017:1-24.
- [7]赵景红,王海龙,杨鹏,等.变压器油中溶解气体奥斯特瓦尔德系数的测定方法[J].分析化学,2005,33(4):471-474.ZHAO Jinghong,WANG Hailong,YANG Peng,et al.Determination of the Ostwald coefficient of dissolved gases in transformer oil with gas chromatography[J].Chinese Journal of Analytical Chemistry,2005,33(4):471-474.
- [8]尹惠,韩秋篁,王飞鹏,等.植物与矿物绝缘油热故障产气差异性分析[J].重庆大学学报,2022,45(1):79-86.YIN Hui,HAN Qiuhuang,WANG Feipeng,et al.Difference analysis of gases produced under thermal faults between vegetable and mineral insulating oils[J].Journal of Chongqing University,2022,45(1):79-86.
- [9]张召涛.植物绝缘油中特征气体及油纸吸湿特性与纳米粒子分散稳定性研究[D].重庆:重庆大学,2012:11-13.ZHANG Zhaotao.Study on properties of characteristic gases and moisture absorption of oil-paper and dispersion stability nano-particles in vegetable insulating oils[D].Chongqing:Chongqing University,2012:11-13.
- [10]何清,鲁莽,王瑞珍,等.FR3植物绝缘油中溶解气体奥斯特瓦尔德系数的测定[J].绝缘材料,2018,51(3):70-73.HE Qing,LU Mang,WANG Ruizhen,et al.Determination of Ostwald coefficients of dissolved gases in FR3vegetable insulating oil[J].Insulating Materials,2018,51(3):70-73.
- [11]杨涛,寇晓适,潘好伟,等.热故障下天然酯绝缘油中溶解气体分析[J].绝缘材料,2018,51(3):74-78.YANG Tao,KOU Xiaoshi,PAN Haowei,et al.Analysis of dissolved gases in natural ester insulating oil under thermal fault[J].Insulating Materials,2018,51(3):74-78.
- [12]GOMEZ N A,WILHELM H M,SANTOS C C,et al.Dissolved gas analysis (DGA) of natural ester insulating fluids with different chemical compositions[J].IEEETransactions on Dielectrics and Electrical Insulation,2014,21(3):1071-1078.
- [13]徐毅,徐言言,袁彬.硅油中Ostwald系数的测定[J].上海大学学报(自然科学版),2017,23(1):73-80.XU Yi,XU Yanyan,YUAN Bin.Determination of Ostwald coefficient in silicone oil[J].Journal of Shanghai University (Natural Science),2017,23(1):73-80.
- [14]YOKOZEKI A.Time-dependent behavior of gas absorption in lubricant oil[J].International Journal of Refrigeration,2002,25:695-704.
- [15]邢海波.滑动轴承润滑油物性及流场特性研究[D].南京:东南大学,2017:11-14.XING Haibo.The research on characteristics of lubricating oil and sliding bearing flow field[D].Nanjing:Southeast University,2017:11-14.
- [16]潘锡林.某微型燃气轮机滑油系统改进设计[D].上海:上海交通大学,2017:1-2.PAN Xilin.Improved design of the lubrication system of a micro gas turbine[D].Shanghai:Shanghai Jiao Tong University,2017:1-2.
- [17]黄梓亮,欧阳小平,赵天菲,等.飞机液压含气量检测系统特性[J].浙江大学学报(工学版),2019,53(1):158-165.HUANG Ziliang,OUYANG Xiaoping,ZHAO Tianfei,et al.Characteristic of air content detection system for aircraft hydraulics[J].Journal of Zhejiang University(Engineering Science),2019,53(1):158-165.
- [18]绝缘油中含气量测定方法真空压差法:DL/T 423-2009[S].北京:中国电力出版社,2009:1-5.Determination of dissolved gas content in insulating oilMethod of vacuum pressure difference:DL/T 423-2009[S].Beijing:China Electric Power Press,2009:1-5.
- [19]绝缘油中含气量的气相色谱测定法:DL/T 703-2015[S].北京:中国电力出版社,2015:1-7.Determination of dissolved gas content in insulating oil by gas chromatography:DL/T 703-2015[S].Beijing:China Electric Power Press,2015:1-7.
- [20]梁学斌,刘永洛,郭海峰,等.氢冷发电机单油环密封油系统改进[J].热力发电,2017,46(10):106-110.LIANG Xuebin,LIU Yongluo,GUO Haifeng,et al.Improvement of single-ring sealing oil system in hydrogen cooled generator[J].Thermal Power Generation,2017,46(10):106-110.
- [21]王笑微,刘永洛,尹文波,等.密封油含气量对氢冷发电机氢气纯度影响研究[J].热力发电,2021,50(4):109-113.WANG Xiaowei,LIU Yongluo,YIN Wenbo,et al.Influence of dissolved gas content in sealing oil on hydrogen purity of hydrogen-cooled generator[J].Thermal Power Generation,2021,50(4):109-113.