磷酸酯抗燃油国产化技术研发及工业应用示范Research and development and industrial application demonstration of the localization technology of phosphate ester fire-resistant fluids
王娟,高占阳,杨大锚,梁永吉,龙国军,王笑微,冯丽苹,谢佳林,刘钊,张晋玮,文乐
摘要(Abstract):
磷酸酯抗燃油作为汽轮机调速系统液压工作介质,对汽轮机正常运转起着至关重要的作用。目前,国内发电机组汽轮机调速系统用磷酸酯抗燃油被进口产品垄断,为打破电力行业高度依赖进口抗燃油的局面,需开展磷酸酯抗燃油国产化研制及应用工作。通过对不同种类国产三芳基磷酸酯性能评价分析,确定适用于国产抗燃油研发的三-(二甲基苯基)磷酸酯;采用氧化和吸附工艺对国产三-(二甲基苯基)磷酸酯进行精制处理,显著提升了三-(二甲基苯基)磷酸酯稳定性能,研制出高性能磷酸酯抗燃油基础油;通过多种添加剂研究,确定添加剂复配方案,得到满足《电厂用磷酸酯抗燃油运行维护导则》(DL/T 571—2014)中新油要求的高性能磷酸酯抗燃油;国产抗燃油静态和动态模拟老化实验研究表明,国产磷酸酯抗燃油抗老化性能优于市售抗燃油;国产磷酸酯抗燃油在发电机组开展1年的工业示范应用期间,油质长期处于新油水平,发电机组调速系统运行正常。
关键词(KeyWords): 三芳基磷酸酯;基础油;添加剂;动态模拟;国产化;工业应用
基金项目(Foundation): 中国华能集团有限公司科技项目(HNKJ23-H22)~~
作者(Author): 王娟,高占阳,杨大锚,梁永吉,龙国军,王笑微,冯丽苹,谢佳林,刘钊,张晋玮,文乐
DOI: 10.19666/j.rlfd.202503039
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