太阳能热化学储能技术关键材料研究现状Research status of key materials for solar thermochemical energy storage technology
胡若兰,邓巍,赵勇,谢小军,张恩享
摘要(Abstract):
回顾了近年来太阳能驱动的固-气、气-气和液-气热化学储能体系应用的反应物和催化剂等关键材料的研究进展;综述了碳酸盐、氢氧化物、金属氢化物、金属氧化物、有机物和氨等材料的热化学储能特性以及反应物材料改性、新材料开发和催化剂改良等的研究现状。目前,适用于太阳能热化学储能的反应物材料在循环稳定性、反应活性、转化率、储能密度、成本或安全性等方面或多或少存在不足,限制了太阳能热化学储能技术的商业化应用。未来,仍需在已知热化学反应体系的基础上研制兼顾储能密度和循环反应稳定性、无腐蚀性和无毒性且具有成本效益的先进复合材料,同时开发新型高效催化剂以提高反应速率,扩展示范应用场景和规模,进一步提升太阳能热化学储能技术的成熟度。
关键词(KeyWords): 太阳能利用;热化学储能;储能材料;反应物;催化剂
基金项目(Foundation): 中国华能集团有限公司总部科技项目(HNKJ22-H21)~~
作者(Author): 胡若兰,邓巍,赵勇,谢小军,张恩享
DOI: 10.19666/j.rlfd.202408192
参考文献(References):
- [1]王树义,张雪峰.“双碳”背景下可再生能源消纳保障机制的软法之治[J].南京工业大学学报(社会科学版),2023,22(6):21-35.WANG Shuyi,ZHANG Xuefeng.Soft law governance of renewable energy absorption guarantee mechanism under the background of“Dual Carbon”[J].Journal of Nanjing Tech University (Social Science Edition),2023,22(6):21-35.
- [2]MERCHáN R P,SANTOS M J,MEDINA A,et al.High temperature central tower plants for concentrated solar power:2021 overview[J].Renewable and Sustainable Energy Reviews,2022,155(1):111828.
- [3]KHAN M I,ASFAND F,AL-GHAMDI S G.Progress in research and technological advancements of commercial concentrated solar thermal power plants[J].Solar Energy,2023,249(1):183-226.
- [4]PRASAD J K,MUTHUKUMAR P,DESAI F,et al.Acritical review of high-temperature reversible thermochemical energy storage systems[J].Applied Energy,2019,254(1):113733.
- [5]CHEN X Y,ZHANG Z,QI C G,et al.State of the art on the high-temperature thermochemical energy storage systems[J].Energy Conversion and Management,2018,177(1):792-815.
- [6]PELAY U,LUO L A,FAN Y L,et al.Thermal energy storage systems for concentrated solar power plants[J].Renewable and Sustainable Energy Reviews,2017,79:82-100.
- [7]QURESHI Z A,ALI H M,KHUSHNOOD S.Recent advances on thermal conductivity enhancement of phase change materials for energy storage system:a review[J].International Journal of Heat and Mass Transfer,2018,127:838-856.
- [8]PRIETO C,COOPER P,FERNáNDEZ A I,et al.Review of technology:thermochemical energy storage for concentrated solar power plants[J].Renewable and Sustainable Energy Reviews,2016,60(1):909-929.
- [9]HAN X Y,WANG L,LING H S,et al.Critical review of thermochemical energy storage systems based on cobalt,manganese,and copper oxides[J].Renewable and Sustainable Energy Reviews,2022,158(1):112076.
- [10]YAN T,WANG R Z,LI T X,et al.A review of promising candidate reactions for chemical heat storage[J].Renewable and Sustainable Energy Reviews,2015,43(1):13-31.
- [11]汪德良,张纯,杨玉,等.基于太阳能光热发电的热化学储能体系研究进展[J].热力发电,2019,48(7):1-9.WANG Deliang,ZHANG Chun,YANG Yu,et al.Research progress of thermochemical energy storage system based on solar thermal power generation[J].Thermal Power Generation,2019,48(7):1-9.
- [12]PARDO P,DEYDIER A,ANXIONNAZ-MINVIELLE Z,et al.A review on high temperature thermochemical heat energy storage[J].Renewable and Sustainable Energy Reviews,2014,32:591-610.
- [13]XU T X,TIAN X K,KHOSA A A,et al.Reaction performance of Ca CO3/Ca O thermochemical energy storage with Ti O2 dopant and experimental study in a fixed-bed reactor[J].Energy,2021,236:121451.
- [14]CHOI D,SHIN J,PARK Y.Effects of Ca Cl2 on cyclic carbonation-calcination kinetics of Ca O-based composite for potential application to solar thermochemical energy storage[J].Chemical Engineering Science,2021,230(1):116207.
- [15]ZHANG Y H,LI Y J,XU Y F,et al.Ca O/Ca CO3thermochemical energy storage performance of Mg O/Zn O co-doped Ca O honeycomb in cycles[J].Journal of Energy Storage,2023,66(1):107447.
- [16]XU Y Q,ZHANG T,LU B W,et al.Glycine tailored effective Ca O-based heat carriers for thermochemical energy storage in concentrated solar power plants[J].Energy Conversion and Management,2021,250(1):114886.
- [17]XU Y Q,LU B W,LUO C,et al.Na2CO3 promoted Ca O-based heat carrier for thermochemical energy storage in concentrated solar power plants[J].Chemical Engineering Journal,2022,435:134852.
- [18]HU Y C,CHEN Y J,FU R C,et al.Steam reactivation of spent Ca O/Ca CO for thermochemical energy storage[J].Solar Energy,2023,255(1):138-145.
- [19]ZHENG H B,SONG C,BAO C,et al.Dark calcium carbonate particles for simultaneous full-spectrum solar thermal conversion and large-capacity thermochemical energy storage[J].Solar Energy Materials and Solar Cells,2020,207:110364.
- [20]PEREJóN A,VALVERDE J M,MIRANDA-PIZARROJ,et al.Large-scale storage of concentrated solar power from industrial waste[J].ACS Sustainable Chemistry&Engineering,2017,5(3):2265-2272.
- [21]BENITEZ-GUERRERO M,VALVERDE J M,SANCHEZ-JIMENEZ P E,et al.Calcium-looping performance of mechanically modified Al2O3-Ca Ocomposites for energy storage and CO2 capture[J].Chemical Engineering Journal,2018,334:2343-2355.
- [22]LAURO F D,TREGAMBI C,MONTAGNARO F,et al.Improving the performance of calcium looping for solar thermochemical energy storage and CO2 capture[J].Fuel,2021,298:120791.
- [23]ANDRéL,ABANADES S.Evaluation and performances comparison of calcium,strontium and barium carbonates during calcination/carbonation reactions for solar thermochemical energy storage[J].Journal of Energy Storage,2017,13:193-205.
- [24]AMGHAR N,ORTIZ C,PEREJóN A,et al.The Sr CO3/Sr O system for thermochemical energy storage at ultra-high temperature[J].Solar Energy Materials and Solar Cells,2022,238(1):111632.
- [25]BAGHERISERESHKI E,TRAN J,LEI F Q,et al.Investigation into Sr O/Sr CO3 for high temperature thermochemical energy storage[J].Solar Energy,2018,160(1):85-93.
- [26]WILLIAMSON K,LIU Y R,HUMPHRIES T D,et al.Thermochemical energy storage in Sr CO3 composites with Sr Ti O3 or Sr Zr O3[J].Energy,2024,292(1):130524.
- [27]SHKATULOV A I,KIM S T,MIURA H,et al.Adapting the Mg O-CO2 working pair for thermochemical energy storage by doping with salts[J].Energy Conversion and Management,2019,185(1):473-481.
- [28]YAN J,ZHAO C Y,PAN Z H.The effect of CO2 on Ca(OH)2 and Mg(OH)2 thermochemical heat storage systems[J].Energy,2017,124:114-123.
- [29]SCHAUBE F,KOCH L,W?RNER A,et al.Athermodynamic and kinetic study of the de-and rehydration of Ca(OH)2 at high H2O partial pressures for thermo-chemical heat storage[J].Thermochimica Acta,2012,538:9-20.
- [30]CRIADO Y A,ALONSO M,ABANADES J C.Kinetics of the Ca O/Ca(OH)2 hydration/dehydration reaction for thermochemical energy storage applications[J].Industrial&Engineering Chemistry Research,2014,53(32):12594-12601.
- [31]XU M,HUAI X L,CAI J.Agglomeration behavior of calcium hydroxide/calcium oxide as thermochemical heat storage material:a reactive molecular dynamics study[J].The Journal of Physical Chemistry C,2017,121(5):3025-3033.
- [32]LUO J W,CHEN L,WANG M Y,et al.Particle-scale study of coupled physicochemical processes in Ca(OH)2dehydration using the lattice Boltzmann method[J].Energy,2022,250(1):123835.
- [33]AFFLERBACH S,KAPPES M,GIPPERICH A,et al.Semipermeable encapsulation of calcium hydroxide for thermochemical heat storage solutions[J].Solar Energy,2017,148:1-11.
- [34]BIAN Z G,LI Y J,FANG Y,et al.Thermochemical heat storage performance and structural stability of Si O2-coated Ca O particles under fluidization in Ca O/Ca(OH)2cycles[J].Journal of Energy Storage,2024,85(1):111102.
- [35]KARIYA J,RYU J,KATO Y.Development of thermal storage material using vermiculite and calcium hydroxide[J].Applied Thermal Engineering,2016,94(1):186-192.
- [36]YAN J,ZHAO C Y.Thermodynamic and kinetic study of the dehydration process of Ca O/Ca(OH)2 thermochemical heat storage system with Li doping[J].Chemical Engineering Science,2015,138(1):86-92.
- [37]PARDO P,ANXIONNAZ-MINVIELLE Z,ROUGéS,et al.Ca(OH)2/Ca O reversible reaction in a fluidized bed reactor for thermochemical heat storage[J].Solar Energy,2014,107:605-616.
- [38]SAKELLARIOU K G,KARAGIANNAKIS G,CRIADOY A,et al.Calcium oxide based materials for thermochemical heat storage in concentrated solar power plants[J].Solar Energy,2015,122(1):215-230.
- [39]SHKATULOV A I,RYU J,KATO Y,et al.Composite material“Mg(OH)2/vermiculite”:a promising new candidate for storage of middle temperature heat[J].Energy,2012,44(1):1028-1034.
- [40]KOBAYASHI N,KUROSAWA R,RYU J.Dehydration reactivity of Mg(OH)2 containing low amounts of Liadditives for thermochemical energy storage[J].ISIJInternational,2022,62(12):2551-2558.
- [41]TIAN Z H,ZHANG J G,ZHANG Y H,et al.Thermochemical heat storage performance of Fe-doped Mg O/Mg(OH)2:experimental and DFT investigation[J].Journal of Energy Storage,2024,86:111388.
- [42]D’ENTREMONT A,CORGNALE C,HARDY B,et al.Simulation of high temperature thermal energy storage system based on coupled metal hydrides for solar driven steam power plants[J].International Journal of Hydrogen Energy,2018,43(2):817-830.
- [43]MANICKAM K,MISTRY P,WALKER G,et al.Future perspectives of thermal energy storage with metal hydrides[J].International Journal of Hydrogen Energy,2019,44(15):7738-7745.
- [44]DELHOMME B,DE RANGO P,MARTY P,et al.Large scale magnesium hydride tank coupled with an external heat source[J].International Journal of Hydrogen Energy,2012,37(11):9103-9111.
- [45]FELDERHOFF M,BOGDANOVI?B.High temperature metal hydrides as heat storage materials for solar and related applications[J].International Journal of Molecular Sciences,2009,10(1):325-344.
- [46]POUPIN L,HUMPHRIES T D,PASKEVICIUS M,et al.An operational high temperature thermal energy storage system using magnesium iron hydride[J].International Journal of Hydrogen Energy,2021,46(78):38755-38767.
- [47]POUPIN L,HUMPHRIES T D,PASKEVICIUS M,et al.A thermal energy storage prototype using sodium magnesium hydride[J].Sustainable Energy&Fuels,2019,3(4):985-995.
- [48]LIU H Z,WANG X H,LIU Y A,et al.Hydrogen desorption properties of the Mg H2-Al H3 composites[J].The Journal of Physical Chemistry C,2014,118(1):37-45.
- [49]OUYANG L Z,YANG X S,ZHU M,et al.Enhanced hydrogen storage kinetics and stability by synergistic effects of in situ formed Ce H2.73 and Ni in Ce H2.73-Mg H2-Ni nanocomposites[J].The Journal of Physical Chemistry C,2014,118(15):7807-7820.
- [50]SINGH M K,BHATNAGAR A,PANDEY S K,et al.Experimental and first principle studies on hydrogen desorption behavior of graphene nanofibre catalyzed Mg H2[J].International Journal of Hydrogen Energy,2017,42(2):960-968.
- [51]WU D F,LI R,SUN T,et al.Enhance Mg-based heat storage materials kinetics by complex oxides[J].Materials Today Communications,2021,29:102767.
- [52]SOFIANOS M V,RANDALL S,PASKEVICIUS M,et al.Exploring halide destabilised calcium hydride as a hightemperature thermal battery[J].Journal of Alloys and Compounds,2019,819:153340.
- [53]DESAGE L,HUMPHRIES T D,PASKEVICIUS M,et al.Calcium hydride with aluminium for thermochemical energy storage applications[J].Sustainable Energy&Fuels,2024,8(1):142-149.
- [54]WU S K,ZHOU C,DOROODCHI E,et al.A review on high-temperature thermochemical energy storage based on metal oxides redox cycle[J].Energy Conversion and Management,2018,168(1):421-453.
- [55]CARRILLO A J,SASTRE D,SERRANO D P,et al.Revisiting the Ba O2/Ba O redox cycle for solar thermochemical energy storage[J].Physical Chemistry Chemical Physics.2016,18(11):8039-8048.
- [56]LEI F Q,DYALL A,AUYEUNG N.An in-depth investigation of Ba O2/Ba O redox oxides for reversible solar thermochemical energy storage[J].Solar Energy Materials and Solar Cells,2021,223(1):110957.
- [57]PAGKOURA C,KARAGIANNAKIS G,ZYGOGIANNIA,et al.Cobalt oxide based honeycombs as reactors/heat exchangers for redox thermochemical heat storage in future CSP plants[J].Energy Procedia,2015,69(1):978-987.
- [58]BLOCK T,SCHMüCKER M.Metal oxides for thermochemical energy storage:a comparison of several metal oxide systems[J].Solar Energy,2016,126(1):195-207.
- [59]NEISES M,TESCARI S,DE OLIVEIRA L,et al.Solarheated rotary kiln for thermochemical energy storage[J].Solar Energy,2012,86(10):3040-3048.
- [60]ANDRéL,ABANADES S,FLAMANT G.Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage[J].Renewable and Sustainable Energy Reviews,2016,64(1):703-715.
- [61]ANDRéL,ABANADES S,CASSAYRE L.Hightemperature thermochemical energy storage based on redox reactions using Co-Fe and Mn-Fe mixed metal oxides[J].Journal of Solid State Chemistry,2017,253:6-14.
- [62]HAN X Y,WANG L,GE Z W,et al.Al-and Cr-doped Co3O4/Co O redox materials for thermochemical energy storage in concentrated solar power plants[J].Solar Energy Materials and Solar Cells,2023,260(1):112475.
- [63]LIU L,ZHOU Z J,CAO X E,et al.Screening of optimal dopants on cobalt-based ceramics for high-temperature thermochemical energy storage[J].Ceramics International,2023,49(2):2329-2339.
- [64]HUANG Y,ZHU P W,GU C D,et al.Investigations on substituted Si-doped Mn2O3/Mn3O4 redox pair for thermochemical energy storage[J].Journal of Energy Storage,2023,73(1):108804.
- [65]HUANG Y,ZHU P W,XU H R,et al.Mn-based oxides modified with Mn Si O3 for thermochemical energy storage[J].Chemical Engineering Journal,2024,483(1):149437.
- [66]AI-SHANKITI I A,EHRHART B D,WARD B J,et al.Particle design and oxidation kinetics of iron-manganese oxide redox materials for thermochemical energy storage[J].Solar Energy,2019,183(1):17-29.
- [67]JIN F,XU C,YU H Y,et al.Ca Co0.05Mn0.95O3-δ:Apromising perovskite solid solution for solar thermochemical energy storage[J].ACS Applied Materials&Interfaces,2021,13(3):3856-3866.
- [68]靳菲,徐超,张华静,等.Zr掺杂Ca Mn O3钙钛矿固溶体太阳能高温热化学储热性能研究[J].中国科学:技术科学,2022,52(8):1223-1232.JIN F,XU C,ZHANG H J,et al.Investigation of Zr-doped Ca Mn O3 perovskite solid solution for high-temperature solar thermochemical energy storage[J].Scientia Sinica Technologica,2022,52(8):1223-1232.
- [69]QIAN X,HE J G,MASTRONARDO E,et al.Outstanding properties and performance of Ca Ti0.5Mn0.5O3-δ for solardriven thermochemical hydrogen production[J].Matter,2021,4(2):688-708.
- [70]KLAAS L,BULFIN B,KRIECHBAUMER D,et al.Impact of the Sr content on the redox thermodynamics and kinetics of Ca1-x Srx Mn O3-δ for tailored properties[J].Physical Chemistry Chemical Physics,2023,25(13):9188-9197.
- [71]SáNCHEZ M.Experimental assessment of Fe-doped Ca Mn O porous pellets in a bench-scale packed-bed reactor for thermochemical energy storage[J].Journal of Energy Storage,2023,57(1):106226.
- [72]QIANG J L,WANG D H,CHU H,et al.Thermochemical energy storage properties of A1-x Srx TO3-δ (A=La,Ba,T=Co,Fe,Ni) perovskite oxides[J].Reaction Kinetics,Mechanisms and Catalysis,2023,136(4):2359-2378.
- [73]WILSON G E,SEYMOUR I D,CAVALLARO A,et al.Fast redox kinetics in Sr Co1-x Sbx O3-δ perovskites for thermochemical energy storage[J].Journal of The Electrochemical Society,2022,169(4):044509.
- [74]MA Q,LUO L,WANG R Z,et al.A review on transportation of heat energy over long distance:exploratory development[J].Renewable and Sustainable Energy Reviews,2009,13(6/7):1532-1540.
- [75]YU T,YUAN Q Y,LU J F,et al.Thermochemical storage performances of methane reforming with carbon dioxide in tubular and semi-cavity reactors heated by a solar dish system[J].Applied Energy,2017,185:1994-2004.
- [76]SAID S A M,WASEEUDDIN M,SIMAKOV D S A.Areview on solar reforming systems[J].Renewable and Sustainable Energy Reviews,2016,59(1):149-159.
- [77]LU J F,DONG Y X,WANG Y R,et al.High efficient thermochemical energy storage of methane reforming with carbon dioxide in cavity reactor with novel catalyst bed under concentrated sun simulator[J].Renewable Energy,2022,188(1):361-371.
- [78]CHEN Q,DONG Y X,DING J,et al.Thermochemical energy storage analysis of solar driven carbon dioxide reforming of methane in Si C-foam cavity reactor[J].Renewable Energy,2024,224(1):120192.
- [79]RIAZ A,KREMER F,KIM T,et al.Experimental demonstration of vanadium-doped nanostructured ceria for enhanced solar thermochemical syngas production[J].Nano Energy,2021,81(1):105639.
- [80]WANG H S,YANG R F,WANG B Z,et al.Thermodynamic performance of solar-driven methanol steam reforming system for carbon capture and highpurity hydrogen production[J].Applied Thermal Engineering,2022,209(1):118280.
- [81]CHEN C,LOVEGROVE K M,SEPULVEDA A E,et al.Design and optimization of an ammonia synthesis system for ammonia-based solar thermochemical energy storage[J].Solar Energy,2018,159(1):992-1002.
- [82]DENG Z H,HU T,TIAN J M,et al.Performance of a novel single-tubular ammonia-based reactor driven by concentrated solar power[J].Solar Energy,2020,204:696-707.
- [83]AGRAFIOTIS C,THOMEY D,DE OLIVEIRA L,et al.Solar energy conversion and storage through sulphurbased thermochemical cycles implemented on centrifugal particle receivers[J].AIP Conference Proceedings,2020,2303(1):170001.
- [84]WONG B,BROWN L,BUCKINGHAM R,et al.Sulfur dioxide disproportionation for sulfur based thermochemical energy storage[J].Solar Energy,2015,118(1):134-144.
- [85]KLINSODA I,PIUMSOMBOON P.Isopropanolacetone-hydrogen chemical heat pump:a demonstration unit[J].Energy Conversion and Management,2007,48(4):1200-1207.
- [86]MOOKSUWAN W,KUMAR S.Study on 2-propanol/acetone/hydrogen chemical heat pump:endothermic dehydrogenation of 2-propanol[J].International Journal of Energy Research,2000,24:1109-1122.