中高温热化学储热材料研究进展Research progress on thermochemical heat storage materials for medium to high temperature applications
陈秋宇,李文涛,李竺豫,张怡,李胜,高丽娟,李凯
摘要(Abstract):
可再生能源在利用过程中存在瞬时性、不稳定性以及供应与需求不匹配等问题。热化学储热技术具有储能密度大、储热温度高等特点,能够实现高效长时储热,可以将不稳定的可再生能源转化为稳定的中高温热能,并满足用户侧的波动需求。针对工作温度范围为400~1 100℃的中高温热化学储热材料,阐述了其分类、基本原理和特点,系统总结了碳酸盐、氢氧化物、氧化物、金属氢化物、氨和甲烷等典型热化学储热材料及其储热性能,分析了其结构定向调控及改性方法,并对典型的工程应用进行了介绍;分析了固-气和气-气反应体系的反应器设计及系统集成的研究进展,并针对优质热化学储能材料在开发及工业应用方面存在的问题,指出了未来的发展方向。
关键词(KeyWords): 热化学储热;中高温;储热材料
基金项目(Foundation): 国家自然科学基金项目(52276188);; 江苏省碳达峰碳中和科技创新专项(BE2022307);; “西安英才计划”青年人才项目(XAYCQN21002)~~
作者(Author): 陈秋宇,李文涛,李竺豫,张怡,李胜,高丽娟,李凯
DOI: 10.19666/j.rlfd.202403033
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