集成化学链制氢的CO2零排放SOFC/GT/ORC混合动力系统性能Performance study of CO2 zero emission SOFC/GT/ORC hybrid power system integrated with chemical chain hydrogen production
佟勇婧,王军,池立勋,程思昱,段立强,张汉飞,王秋实,王浩博,黄龑
摘要(Abstract):
提出一种新型集成化学链制氢的CO_2零排放固体氧化物燃料电池/燃气轮机/有机朗肯循环混合动力系统,在实现高效发电的同时,高效分离捕集CO_2。系统以甲烷为燃料,通过化学链反应产生氢气进入燃料电池,避免了电池内部积碳现象发生,电池阳极出口回路至化学链,燃料反应器出口与电池阴极出口气体进入燃气轮机做功,排气余热被有机朗肯循环系统回收利用,进一步提高系统效率;并建立了系统模型并进行热力学性能分析,得到系统性能随燃料流量、燃料利用率、电池工作温度及系统工作压力的变化规律。结果表明:系统综合能源利用效率可达74.10%以上,电效率可达62.42%以上,?效率达到57.73%;敏感性分析表明,系统工作压力达到7×10~5 Pa时,系统性能达到最优。
关键词(KeyWords): 固体氧化物燃料电池;化学链制氢;分布式发电系统;热力学性能
基金项目(Foundation): 中石油昆仑燃气有限公司科学研究与技术开发项目(2023-KLKJ-10)~~
作者(Author): 佟勇婧,王军,池立勋,程思昱,段立强,张汉飞,王秋实,王浩博,黄龑
DOI: 10.19666/j.rlfd.202409206
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