蒙毅,刘逸芸,宋士林,刘玺璞

• 1:西安西热锅炉环保工程有限公司

摘要(Abstract)：

碳酸氢铵固体是一种潜在的脱硝还原剂，可以通过固体直接热解高效制取氨气。通过数值计算模拟了碳酸氢铵固体热解反应，并设计了适用于燃煤电厂的热解制氨系统，分析了碳酸氢铵热解制氨过程的经济性。模拟结果显示，碳酸氢铵热解过程适宜在常压下进行，反应温度在100℃以上时热解转化率迅速提高。对660 MW机组的碳酸氢铵热解系统进行了设计计算，采用外热式热解反应器以实现余热利用和固体稳定进料，利用燃煤电厂蒸汽或烟气作为热解热源，在110℃时碳酸氢铵进料在10 min内可以达到95%转化率。相比尿素水解制氨工艺，碳酸氢铵固体热解工艺的设备成本、占地面积和运行费用均显著降低，具有良好的推广应用前景。

关键词(KeyWords)： 碳酸氢铵;固体热解;制氨;模拟;燃煤电厂

Abstract:

Keywords:

基金项目(Foundation): 中国华能集团有限公司总部科技项目（HNKJ22-H124）~~

作者(Author): 蒙毅,刘逸芸,宋士林,刘玺璞

DOI: 10.19666/j.rlfd.202502010

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