朱文韬,杜振,张杨,罗聪,张立麒

• 1:华电电力科学研究院有限公司
• 2:华中科技大学煤燃烧与低碳利用全国重点实验室

摘要(Abstract)：

针对“双碳”形势下国内煤电机组低碳转型需求，探索CCUS技术工业化固碳新路径，开发可直接用于燃煤烟气CO_2捕集的新型固体化学吸附材料，实现燃煤烟气固体吸附CO_2捕集技术规模化应用具有重要意义。目前，国内固体吸附CO_2捕集技术研究多以分项理论研究为主，对此，系统梳理和分析了低、中、高温固体吸附材料研究进展，指出固体吸附材料研究需拓展的方向，以及实现规模化应用需开展的研究内容。以典型高温钙基吸附剂为例，针对吸附剂放大制备、造粒成型、反应器设计及钙循环CO_2捕集系统验证全过程工业化应用研究进行分析。研究内容可为下一步开展关键技术研究与突破，加快构建高活性低能耗固体吸附捕集CO_2的全流程装备技术体系，实现固体吸附CO_2捕集技术规模化应用提供参考。

关键词(KeyWords)： 燃煤烟气;固体吸附;CO_2捕集;规模化;钙循环

Abstract:

Keywords:

基金项目(Foundation): 国家重点研发计划项目（2023YFB4104000）;; 中国华电集团有限公司科技项目（CHDK21-01-109,CHDKJ24-04-01-29）~~

作者(Author): 朱文韬,杜振,张杨,罗聪,张立麒

DOI: 10.19666/j.rlfd.202411232

参考文献(References)：

• [1]刘兰.全球极端天气走向常态化[J].生态经济,2021,37(9):5-8.LIU Lan.Global extreme weather is becoming normal[J].Ecological Economy,2021,37(9):5-8.
• [2]CHEN S Y,LIU J F,ZHANG Q,et al.A critical review on deployment planning and risk analysis of carbon capture,utilization,and storage (CCUS) toward carbon neutrality[J].Renewable and Sustainable Energy Reviews,2022,167:112537.
• [3]蔡博峰,李琦,张贤,等.《中国二氧化碳捕集利用与封存(CCUS)年度报告(2021)--中国CCUS路径研究》[R].北京:生态环境部环境规划院,中国科学院武汉岩土力学研究所,21世纪议程管理中心,2021:1.CAI Bofeng,LI Qi,ZHANG Xian,et al.China carbon dioxide capture,utilization and storage (CCUS) annual report (2021):research on China’s CCUS pathway[R].Beijing:Institute of Environmental Planning,Ministry of Ecology and Environment,Wuhan Institute of Rock and Soil Mechanics,Chinese Academy of Sciences,Center for Agenda 21 Management,2021:1.
• [4]张贤,李阳,马乔,等.我国碳捕集利用与封存技术发展研究[J].中国工程科学,2021,23(6):70-80.ZHANG Xian,LI Yang,MA Qiao,et al.Development of carbon capture,utilization and storage technology in China[J].Strategic Study of CAE,2021,23(6):70-80.
• [5]胡永乐,郝明强.CCUS产业发展特点及成本界限研究[J].油气藏评价与开发,2020,10(3):15-22.HU Yongle,HAO Mingqiang.Development characteristics and cost analysis of CCUS in China[J].Reservoir Evaluation and Development,2020,10(3):15-22.
• [6]2023年政府工作报告[EB/OL].(2023-03-05)[2024-11-01].https://www.gov.cn/zhuanti/2023lhzfgzbg/index.htm.Report on the work of the government for 2023[EB/OL].(2023-03-05)[2024-11-01].https://www.gov.cn/zhuanti/2023lhzfgzbg/index.htm.
• [7]蒲鹤,梁光川,何慧娟,等.燃煤电厂尾气中CO2捕集技术研究[J].天然气与石油,2013,31(6):52-54.PU He,LIANG Guangchuan,HE Huijuan,et al.Study on CO2 capture technology for coal-fired power plant tail gas[J].Natural Gas and Oil,2013,31(6):52-54.
• [8]梁明星.用于吸收燃煤电厂烟气中CO2混合胺吸收剂研究[D].北京:北京化工大学,2017:1.LIANG Mingxing.Study on mixed amine absorbents CO2 absorption in flue gas of coal-fired power plant[D].Beijing:Beijing University of Chemical Technology,2017:1.
• [9]高炜,白平,王鸿,等.CCUS项目的温室气体排放核算方法学思考[J].中国国土资源经济,2022,35(4):12-21.GAO Wei,BAI Ping,WANG Hong,et al.Consideration on greenhouse gas emission accounting methodology of CCUS project[J].Natural Resource Economics of China,2022,35(4):12-21.
• [10]赵淑媛,袁鑫,刘骏,等.“双碳”背景下CCUS应用对火电机组经济性的影响分析[J].能源科技,2022,20(5):39-43.ZHAO Shuyuan,YUAN Xin,LIU Jun,et al.Analysis of the impact of CCUS application on the efficiency of thermal power units in the context of"carbon peak and carbon neutrality"[J].Energy Science and Technology,2022,20(5):39-43.
• [11]中国石油新闻中心.共话CCUS发展前景共创低碳美好未来:第七届碳捕集利用与封存国际论坛专家发言摘登[EB/OL].(2023-03-20)[2024-11-01].http://news.cnpc.com.cn/system/2023/03/20/030096082.shtml.China Petroleum News Center.CCUS development prospects for a low-carbon future:excerpts from the 7th International forum on carbon capture,utilization and storage[EB/OL].(2023-03-20)[2024-11-01].http://news.cnpc.com.cn/system/2023/03/20/030096082.shtml.
• [12]张帆,林志坚,方飞.国内外碳捕集技术发展现状分析[J].能源化工,2022,43(5):13-19.ZHANG Fan,LIN Zhijian,FANG Fei,et al.Analysis on the development status of carbon capture technology[J].Energy Chemical Industry,2022,43(5):13-19.
• [13]温翯,韩伟,车春霞,等.燃烧后二氧化碳捕集技术与应用进展[J].精细化工,2022,39(8):1583-1632.WEN He,HAN Wei,CHE Chunxia,et al.Progress of post-combustion carbon dioxide capture technology development and applications[J].Fine Chemicals,2022,39(8):1583-1632.
• [14]兰林,徐飞,夏林,等.变压吸附技术在工业化碳捕集中的应用现状[J].天然气与石油,2024,42(2):21-28.LAN Lin,XU Fei,XIA Lin,et al.Application status of pressure swing adsorption technology in industrial carbon capture[J].Natural Gas and Oil,2024,42(2):21-28.
• [15]刘强,肖金,于航,等.变压吸附捕集CO2技术研究进展及其在石化行业应用案例分析[J].南方能源建设,2024,11(5):37-49.LIU Qiang,XIAO Jin,YU Hang,et al.Research progress of pressure swing adsorption CO2 capture technology and case analysis of its application in petrochemical industry[J].Southern Energy Construction,2024,11(5):37-49.
• [16]陆诗建,贡玉萍,刘玲,等.有机胺CO2吸收技术研究现状与发展方向[J].洁净煤技术,2022,28(9):44-54.LU Shijian,GONG Yuping,LIU Ling,et al.Research status and future development direction of CO2absorption technology for organic amine[J].Clean Coal Technology,2022,28(9):44-54.
• [17]胡长征,王雅博,刘圣春.MEA溶液在生物质电厂和燃煤电厂捕集CO2应用对比[J].综合智慧能源,2022,44(6):78-85.HU Changzheng,WANG Yabo,LIU Shengchun.Application of MEA solution in the CO2 capture in biomass power plants and coal-fired power plants[J].Integrated Intelligent Energy,2022,44(6):78-85.
• [18]WANG L D,AN S L,YU S H,et al.Mass transfer characteristics of CO2 absorption into a phase-change solvent in a wetted-wall column[J].International Journal of Greenhouse Gas Control,2017,64:276-283.
• [19]WANG R J,JIANG L,LI Q W,et al.Energy-saving CO2capture using sulfolane-regulated biphasic solvent[J].Energy,2020,211:118667.
• [20]SINGH A,STéPHENNE K.Shell cansolv CO2 capture technology:achievement from first commercial plant[J].Energy Procedia,2014,63:1678-1685.
• [21]刁保圣,顾欣,冯琰磊.大规模二氧化碳捕集及综合利用示范[J].锅炉技术,2021,52(6):76-80.DIAO Baosheng,GU Xin,FENG Yanlei,et al.Large scale carbon dioxide capture and comprehensive utilization demonstration[J].Boiler Technology,2021,52(6):76-80.
• [22]CAI T Y,JOHNSON J K,WU Y,et al.Toward understanding the kinetics of CO2 capture on sodium carbonate[J].ACS Applied Materials&Interfaces,2019,11(9):9033-9041.
• [23]江涛,魏小娟,王胜平,等.固体吸附剂捕集CO2的研究进展[J].洁净煤技术,2022,28(1):42-57.JIANG Tao,WEI Xiaojuan,WANG Shengping,et al.Research progress on solid sorbents for CO2 capture[J].Clean Coal Technology,2022,28(1):42-57.
• [24]WANG Z,GOYAL N,LIU L Y,et al.N-doped porous carbon derived from polypyrrole for CO2 capture from humid flue gases[J].Chemical Engineering Journal,2020,396:125376.
• [25]WANG Y Y,HUANG L,YANG R Y,et al.Recent advances in solid sorbents for CO2 capture and new development trends[J].Energy&Environmental Science,2014,7:3478-3518.
• [26]赵传文,陈晓平,赵长遂.碱金属基吸收剂干法脱除CO2技术的研究进展[J].动力工程,2008,28(6):827-833.ZHAO Chuanwen,CHEN Xiaoping,ZHAO Changsui.Research progress of CO2 capture technology using dry alkali-based sorbents[J].Journal of Power Engineering,2008,28(6):827-833.
• [27]赵传文,陈晓平,赵长遂.钾基CO2吸收剂的碳酸化反应特性[J].化工学报,2008,59(9):2328-2333.ZHAO Chuanwen,CHEN Xiaoping,ZHAO Changsui.Carbonation reaction characteristics of dry potassium-based sorbent for CO2 capture[J].Journal of Chemical Industry and Engineering (China),2008,59(9):2328-2333.
• [28]刘燕燕,徐樑,宋凯,等.负载型K2CO3/5A吸附剂的碳酸化反应特性研究[J].化学工程,2018,46(7):12-16.LIU Yanyan,XU Liang,SONG Kai,et al.Carbonation characteristics of supported K2CO3/5A adsorbent[J].Chemical Engineering (China),2018,46(7):12-16.
• [29]曹杰.燃煤飞灰负载K+基吸收剂捕集CO2吸收再生特性研究[D].上海:东华大学,2015:1.CAO Jie.Carbonation and regeneration characteristics of potassium-based sorbents supported by coal fired fly ash for CO2 capture[D].Shanghai:Donghua University,2015:1.
• [30]梅雪松,徐樑,赵传文,等.循环流化床飞灰对钾基吸附剂脱除CO2影响研究[J].热能动力工程,2019,34(2):69-74.MEI Xuesong,XU Liang,ZHAO Chuanwen,et al.Effect of fly ash in CFB in the process of CO2 capture using potassium-based sorbents[J].Journal of Engineering for Thermal Energy and Power,2019,34(2):69-74.
• [31]赵传文,陈晓平,赵长遂.负载型K2CO3/Al2O3二氧化碳吸收剂的碳酸化反应特性[J].化工学报,2009,60(4):1022-1027.ZHAO Chuanwen,CHEN Xiaoping,ZHAO Changsui.Carbonation characteristics of K2CO3/Al2O3 for CO2capture[J].Journal of the Chemical Industry and Engineering Society of China,2009,60(4):1022-1027.
• [32]王彦霖,贾里,梅雪松,等.负载型钾基吸附剂的CO2吸附机理及失效特性[J].环境科学与技术,2019,42(11):98-104.WANG Yanlin,JIA Li,MEI Xuesong,et al.CO2adsorption mechanism of potassium-based adsorbents with different supports[J].Environmental Science&Technology,2019,42(11):98-104.
• [33]雷苏,曾鹏鑫,王鹏,等.Na2CO3基吸附剂颗粒制备及其脱碳性能[J].化工进展,2019,38(8):3562-3571.LEI Su,ZENG Pengxin,WANG Peng,et al.Investigation on granulation and CO2 uptake of Na2CO3-based sorbent pellets[J].Chemical Industry and Engineering Progress,2019,38(8):3562-3571.
• [34]陈少卿,赵长遂,赵传文.钾基固体吸收剂脱除烟气中CO2技术的研究进展[J].动力工程学报,2010,30(7):542-549.CHEN Shaoqing,ZHAO Changsui,ZHAO Chuanwen.Development of CO2 capture technology using solid potassium-based sorbents[J].Journal of Chinese Society of Power Engineering,2010,30(7):542-549.
• [35]ELVIRA G B,FRANCISCO G C,VI/CTOR S M,et al.Mg O-based adsorbents for CO2 adsorption:influence of structural and textural properties on the CO2 adsorption performance[J].Journal of Environmental Sciences,2017,57(7):418-428.
• [36]DING Y D,SONG G,ZHU X,et al.Synthesizing Mg Owith a high specific surface for carbon dioxide adsorption[J].RSC Advances,2015,5(39):30929-30935.
• [37]GAO W L,ZHOU T T,WANG Q.Controlled synthesis of Mg O with diverse basic sites and its CO2 capture mechanism under different adsorption conditions[J].Chemical Engineering Journal,2018,336:710-720.
• [38]徐运飞,李英杰,王涛,等.Mg O吸附剂捕集CO2的研究进展[J].洁净煤技术,2021,27(1):125-134.XU Yunfei,LI Yingjie,WANG Tao,et al.Research progress on Mg O sorbents for CO2 capture[J].Clean Coal Technology,2021,27(1):125-134.
• [39]GUO Y F,TAN C,WANG P,et al.Magnesium-based basic mixtures derived from earth-abundant natural minerals for CO2 capture in simulated flue gas[J].Fuel,2019,243(5):298-305.
• [40]YANG N,NING P,LI K,et al.A new method of processing CO2 and magnesite slag simultaneously[J].Journal of the Serbian Chemical Society,2019,84:69-82.
• [41]王美慧,刘慧敏,谢跃林,等.改性氧化镁捕集二氧化碳的研究[J].离子交换与吸附,2021,37(4):314-322.WANG Meihui,LIU Huimin,XIE Yuelin,et al.Study of carbon dioxide capture by modified magnesium oxide[J].Ion Exchange and Adsorption,2021,37(4):314-322.
• [42]田甜,张学奇,王玉清,等.含膦多孔有机聚合物负载氧化镁的制备及其CO2吸附性能[J].洁净煤技术,2024,30(4):146-156.TIAN Tian,ZHANG Xueqi,WANG Yuqing,et al.Prepation and CO2 adsorption perforemance of a phosphine-containing porous organic polymer supported magnisium oxide[J].Clean Coal Technology,2024,30(4):146-156.
• [43]BURRI H,ANJUM R,GURRAM R B,et al.Mesoporous carbon supported Mg O for CO2 capture and separation of CO2/N2[J].Korean Journal of Chemical Engineering,2019,36:1482-1488.
• [44]GUO Y F,TAN C,SUN J,et al.Biomass ash stabilized Mg O adsorbents for CO2 capture application[J].Fuel,2020,259:116298.
• [45]左臣盛,周思宇,孙成志,等.变温镁基CO2吸附剂的制备及应用I.Na/Mg物质的量比[J].燃料化学学报,2014,42(7):884-889.ZUO Chensheng,ZHOU Siyu,SUN Chengzhi,et al.Preparation and application of magnesium-based CO2sorbent for temperature swing absorption I.Na/Mg mol ratio[J].Journal of Fuel Chemistry and Technology,2014,42(7):884-889.
• [46]ZHANG K L,LI X S,CHNE H B,et al.Molten salt promoting effect in double salt CO2 absorbents[J].The Journal of Physical Chemistry C,2016,120:1089-1096.
• [47]HARADA T,SIMEON F,HAMAD E Z,et al.Alkali metal nitrate-promoted high-capacity Mg O adsorbents for regenerable CO2 capture at moderate temperatures[J].Chemistry of Materials,2015,27:1943-1949.
• [48]POZZO A D,ARMUTLULU A,REKHTINA M,et al.CO2 uptake and cyclic stability of Mg O-based CO2sorbents promoted with alkali metal nitrates and their eutectic mixtures[J].ACS Applied Energy Materials,2019,2:1295-1307.
• [49]孙吉.碳模板法改性钙基、镁基吸附剂捕获烟气二氧化碳的研究[D].徐州:中国矿业大学,2018:1.SUN Ji.Study on carbon template-modified calcium and magnesium based adsorbents to capture carbon dioxide in flue gas[D].Xuzhou:China University of Mining and Technology,2018:1.
• [50]SONG G,ZHU X,CHEN R,et al.Influence of the precursor on the porous structure and CO2 adsorption characteristics of Mg O[J].RSC Advances,2016,6:19069-19077.
• [51]SHIMIZU T,HIRAMA T,HOSODA H,et al.A twin fluid-bed reactor for removal of CO2 from combustion processes[J].Chemical Engineering Research and Design,1999,77(1):62-68.
• [52]ABANADES J C,GRASA G,ALONSO M,et al.Cost structure of a postcombustion CO2 capture system using Ca O[J].Environmental Science&Technology,2007,41(15):5523-5527.
• [53]LISBONA P,MARTI/NEZ A,LARA Y,et al.Integration of carbonate CO2 capture cycle and coal-fired power plants.A comparative study for different sorbents[J].Energy&Fuels,2010,24:728-736.
• [54]耿一琪,郭彦霞,樊飙,等.Ca O基吸附剂捕集CO2及其抗烧结改性研究进展[J].燃料化学学报,2021,49(7):998-1013.GENG Yiqi,GUO Yanxia,FAN Biao,et al.Research progress of calcium-based adsorbents for CO2 capture and anti-sintering modification[J].Journal of Fuel Chemistry and Technology,2021,49(7):998-1013.
• [55]GRASA G S,ABANADES J C.CO2 capture capacity of Ca O in long series of carbonation/calcination cycles[J].Industrial&Engineering Chemistry Research,2006,45(26):8846-8851.
• [56]代金雨,罗聪,李小姗,等.钙循环热化学储能及其耦合CO2捕集技术研究进展[J].洁净煤技术,2024,30(10):1-18.DAI Jinyu,LUO Cong,LI Xiaoshan,et al.Recent advances on calcium looping thermochemical energy storage and its coupling for CO2 capture[J].Clean Coal Technology,2024,30(10):1-18.
• [57]VAUX W G,KEAIRNS D L.Particle attrition in fluid-bed processes[M]//GRACE J R,MATSEN J M.Fluidization.Springer,Boston,MA,1980:437-444.https://doi.org/10.1007/978-1-4684-1045-7_45.
• [58]FENNELL P S,PACCIANI R,DENNIS J S,et al.The effects of repeated cycles of calcination and carbonation on a variety of different limestones,as measured in a hot fluidized bed of sand[J].Energy&Fuels,2007,21:2072-2081.
• [59]GONZA/LEZ B,ALONSO M,ABANADES J C.Sorbent attrition in a carbonation/calcination pilot plant for capturing CO2 from flue gases[J].Fuel,2010,89(10):2918-2924.
• [60]ARCENEGUI-TROYA J,SA/NCHEZ-JIME/NEZ P E,PEREJO/N A,et al.Kinetics and cyclability of limestone(Ca CO3) in presence of steam during calcination in the Ca L scheme for thermochemical energy storage[J].Chemical Engineering Journal,2021,417(7):129194.
• [61]WITOON T.Characterization of calcium oxide derived from waste eggshell and its application as CO2sorbent[J].Ceramics International,2011,37(8):3291-3298.
• [62]CASTILHO S,KIENNEMANN A,PEREIRA M F C,et al.Sorbents for CO2 capture from biogenesis calcium wastes[J].Chemical Engineering Journal,2013,226(1):146-153.
• [63]马艾华.改性造纸白泥循环捕集二氧化碳的性能研究[D].昆明:昆明理工大学,2016:1.MA Aihua.Study on carbon dioxide recycling performance of modified papermaking white mud[D].Kunming:Kunming University of Science and Technology,2016:1.
• [64]YAN F,JIANG J G,LI K M,et al.Performance of coal fly ash stabilized,Ca O-based sorbents under different carbonation-calcination conditions[J].ACS Sustainable Chemistry&Engineering,2015,3(9):2092-2099.
• [65]TIAN S C,JIANG J G,YAN F,et al.Synthesis of highly efficient Ca O-based,self-stabilizing CO2 sorbents via structure-reforming of steel slag[J].Environmental Science&Technology,2015,49(12):7464-7472.
• [66]BLAMEY J,ANTHONY E J,WANG J,et al.The calcium looping cycle for large-scale CO2 capture[J].Progress in Energy and Combustion Science,2010,36(2):260-279.
• [67]LI Y J,SUN R Y,LIU C T,et al.CO2 capture by carbide slag from chlor-alkali plant in calcination/carbonation cycles[J].International Journal of Greenhouse Gas Control,2012,9:117-123.
• [68]MANOVIC V,ANTHONY E J.Carbonation of Ca O-based sorbents enhanced by steam addition[J].Industrial&Engineering Chemistry Research,2010,49:9105-9110.
• [69]MANOVIC V,ANTHONY E J.Thermal activation of Ca O-based sorbent and self-reactivation during CO2capture looping cycles[J].Environmental Science&Technology,2008,42(11):4170-4174.
• [70]张雪莹.钙基吸收剂的改性及碳捕集性能研究[D].北京:清华大学,2014:1.ZHANG Xueying.Modification of Ca-based sorbents for efficient CO2 mitigation[D].Beijing:Tsinghua University,2014:1.
• [71]WANG C B,JIA L F,TAN Y W,et al.Carbonation of fly ash in oxy-fuel CFB combustion[J].Fuel,2008,87(7):1108-1114.
• [72]ALBRECHT K O,WAGENBACH K S,SATRIO J A,et al.Development of a Ca O-based CO2 sorbent with improved cyclic stability[J].Industrial&Engineering Chemistry Research,2008,47:7841-7848.
• [73]LI Y J,ZHAO C S,CHEN H C,et al.Modified Ca O-based sorbent looping cycle for CO2 mitigation[J].Fuel,2009,88(4):697-704.
• [74]LI Y J,SUN R Y,LIU H L,et al.Cyclic CO2 capture behavior of limestone modified with pyroligneous acid(PA) during calcium looping cycles[J].Industrial&Engineering Chemistry Research,2011,50(17):10222-10228.
• [75]SUN R Y,LI Y J,WU S M,et al.Enhancement of CO2capture capacity by modifying limestone with propionic acid[J].Powder Technology,2013,233:8-14.
• [76]SALVADOR C,LU D,ANTHONY E J,et al.Enhancement of Ca O for CO2 capture in an FBCenvironment[J].Chemical Engineering Journal,2003,96:187-195.
• [77]GONZA/LEZ B,BLAMEY J,MCBRIDE-WRIGHT M,et al.Calcium looping for CO2 capture:sorbent enhancement through doping[J].Energy Procedia,2011,4:402-409.
• [78]徐勇庆.碱金属盐改性钙基吸附剂的碳捕集特性研究[D].武汉:华中科技大学,2020:1.XU Yongqing.Investigation on the CO2 capture characteristics of alkali salt modified Ca O-based adsorbent[D].Wuhan:Huazhong University of Science and Technology,2020:1.
• [79]徐勇庆,鲁博文,张泽武,等.K改性钙基吸附剂的CO2捕集特性研究[J].工程热物理学报,2022,43(8):2106-2110.XU Yongqing,LU Bowen,ZHANG Zewu,et al.Cyclic CO2 capture characteristics of the K modified Ca-based sorbent[J].Journal of Engineering Thermophysics,2022,43(8):2106-2110.
• [80]LI L Y,KING D L,NIE Z,et al.Magnesia-stabilized calcium oxide absorbents withimproved durability for high temperature CO2 capture[J].Industrial&Engineering Chemistry Research,2009,48(23):2106-2110.
• [81]LAN P Q,WU S F.Synthesis of a porous nano-Ca O/Mg O-based CO2 adsorbent[J].Chemical Engineering&Technology,2014,37(4):580-586.
• [82]LI Z S,CAI N S,HUANG Y Y,et al.Synthesis,experimental studies,and analysis of a new calcium-based carbon dioxide absorbent[J].Energy&Fuels,2005,19(4):1447-1452.
• [83]ZHOU Z M,QI Y,XIE M M,et al.Synthesis of Ca O-based sorbents through incorporation of alumina/aluminate and their CO2 capture performance[J].Chemical Engineering Science,2012,74:172-180.
• [84]ZHAO M,BILTON M,ANDY P B,et al.Durability of Ca O-Ca Zr O3 sorbents for high-temperature CO2 capture prepared by a wet chemical method[J].Energy&Fuels,2014,28(2):1275-1283.
• [85]HU Y C,LIU W Q,CHEN H Q,et al.Screening of inert solid supports for Ca O-based sorbents for high temperature CO2 capture[J].Fuel,2016,181:199-206.
• [86]王长清,曾鹏鑫,张禹,等.惰性载体对钙基吸附剂脱碳性能增强作用的研究进展[J].中国电机工程学报,2024,44(22):8936-8948.WANG Changqing,ZENG Pengxin,ZHANG Yu,et al.Research progress on enhancement of decarburization performance of calcium-based adsorbents by inert supporting[J].Proceedings of the CSEE,2024,44(22):8936-8948.
• [87]罗聪.高温钙基循环脱碳机理与反应特性研究[D].武汉:华中科技大学,2013:4.LUO Cong.Mechanism and reaction characteristics of calcium looping cycle for carbon capture at high temperatures[D].Wuhan:Huazhong University of Science and Technology,2013:1.
• [88]MA X T,LI Y J,ZHANG C X,et al.Development of Mn/Mg-copromoted carbide slag for efficient CO2capture under realistic calcium looping conditions[J].Process Safety and Environmental Protection,2020,141:380-389.
• [89]沈辉.氧化钙基吸附剂的制备及其CO2吸附性能研究[D].天津:天津大学,2013:1.SHEN Hui.Research on the preparation and CO2 capture performance of Ca O based adsorbents[D].Tianjin:Tianjin University,2013:1.
• [90]李姗.氧化钙基吸附剂的制备及其CO2高温吸附性能研究[D].天津:天津大学,2019:1.LI Shan.Preparation and high-temperature CO2adsorption performance of Ca O-based sorbents[D].Tianjin:Tianjin University,2019:1.
• [91]王胜平.多壳层空心微球钙基吸附剂吸附二氧化碳构效关系研究[C]//中国化学会·第一届全国二氧化碳资源化利用学术会议摘要集,2019:76.WANG Shengping.Study on the structure-activity relationship of carbon dioxide adsorption by multi-shell hollow microspheres calcium-based adsorbents[C]//Chinese Chemical Society:Abstract Collection of the First National Carbon dioxide Resource Utilization Academic Conference,2019:76.
• [92]郭红霞,南雁,寇晓晨,等.钙基CO2吸附剂的惰性掺杂和形貌调控研究进展[J].化工进展,2019,38(1):457-466.GUO Hongxia,NAN Yan,KOU Xiaochen,et al.Research on doping modification and morphology control of calcium-based CO2 sorbents[J].Chemical Industry and Engineering Progress,2019,38(1):457-466.
• [93]MA X T,LI Y J,DUAN L B,et al.CO2 capture performance of calcium-based synthetic sorbent with hollow core-shell structure under calcium looping conditions[J].Applied Energy,2018,225:402-412.
• [94]TONG X L,LIU W Q,YANG Y D,et al.Asemi-industrial preparation procedure of Ca O-based pellets with high CO2 uptake performance[J].Fuel Processing Technology,2019,193:149-158.
• [95]SUN J,SUN Y,YANG Y D,et al.Plastic/rubber waste-templated carbide slag pellets for regenerable CO2capture at elevated temperature[J].Applied Energy,2019,242:919-930.
• [96]JIANG T,ZHANG H,ZHAO Y J,et al.Kilogram-scale production and pelletization of Al-promoted Ca O-based sorbent for CO2 capture[J].Fuel,2021,301(2):121049.
• [97]SUN J,LIU W Q,HU Y C,et al.Enhanced performance of extruded-spheronized carbide slag pellets for high temperature CO2 capture[J].Chemical Engineering Journal,2016,285:293-303.
• [98]陈鎏竹.钙基复合CO2吸附剂的造孔改性研究[D].武汉:华中科技大学,2015:1.CHEN Liuzhu.Study on the modification of Ca-based composite CO2 sorbents by pore-forming[D].Wuhan:Huazhong University of Science and Technology,