凝结水精处理铵型运行出水氯离子迁移特性Migration characteristics of chloride ions in effluent of ammonium type operation of condensate polishing
左选国,张龙明,贾兰
摘要(Abstract):
实现精处理出水氯离子指标的有效监控,对保障精处理出水水质、运行工艺调整、延长运行周期等具有关键作用。根据离子交换平衡理论,分析比对了精处理氢型与铵型运行方式的运行特点、出水水质以及树脂再生度要求;并通过实验室模拟以及某电厂精处理混床运行周期跟踪试验,重点研究了精处理出水氯离子迁移特性。结果表明:氢型阶段树脂再生度要求低,该阶段主要以除盐为主,不易发生漏氯现象;转化阶段随着出水pH值不断升高,对树脂再生度要求也不断提高,当凝结水中含有氯离子时容易发生氯离子的溢出现象;铵型运行时混床不再以除盐为主,出水氯离子质量浓度与凝结水相当。因此,对于精处理出水(尤其是铵型运行时),实现氯离子有效监控对于保障出水水质是必要的,同时将氯离子作为监控指标之一,不仅可有效保障精处理出水水质,同时可以指导精处理运行工艺调整,在保障机组安全运行的前提下达到显著延长精处理运行周期的目的。
关键词(KeyWords): 凝结水精处理;铵型运行;再生度;氯离子
基金项目(Foundation): 中国华能集团有限公司研究开发基金项目(HNKJ21-HF306)~~
作者(Author): 左选国,张龙明,贾兰
DOI: 10.19666/j.rlfd.202411242
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